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Defect energetics


Let us begin with the first question. For d>2, the topological glass state is a true ordered phase, described by a zero temperature fixed point. The issue then is to determine whether this T=0 fixed point is stable to the introduction of topological defects. To answer this, we must determine if the total ground state energy of the system is reduced relative to its elastic value in a configuration containing such defects at large scales. By present at large scales, we mean unbound defects, so that their presence is felt in long-distance (or small q) correlation functions.

To get an idea of how to think about this question, let us consider a similar problem that arises in the pure two-dimensional XY model, i.e. a two-dimensional CDW with zero disorder. In the elastic approximation, the system has logarithmic correlations at finite temperature, since


The factor of T in from of the expression indicates that the long-distance physics in this case is governed by a finite temperature fixed line. In this case, one would like to know if this fixed line is stable to the introduction of vortices. One can formulate a precise RG calculation, but a simple scaling argument due to Kosterlitz and Thouless gives the correct answer and a good physical picture. Let us ask if a system of size L increases or lowers its free energy by introducing a vortex. The energy cost of a single vortex can be easily calculated. If we place the vortex at the origin, a convenient choice for the phase configuration is tex2html_wrap_inline3776 , the polar angle. Then


which gives the elastic energy cost


where a is a short-distance cutoff (e.g. lattice size). There is also an entropic contribution, which is just the logarithm of the number of positions the vortex may take, or


The total free energy change is thus


Thus, for tex2html_wrap_inline3780 , a vortex costs free energy, and the elastic state is stable. For tex2html_wrap_inline3782 , it is favorable for the vortex to enter the system, and in fact one expects vortices to proliferate and destroy the elastic state.

This argument suggests we should consider the effect of introducing a single topological defect into a system of size L. However, because we are considering the stability of a zero-temperature fixed point, it is simply the energy (and not the free energy) change which must be negative for an instability. This is possible because the system without topological defects is constrained. By releasing the constraint, the system may be able to lower its energy.

In fact, I believe it is guaranteed that the total energy will decrease. This is because there will always be rare regions of the sample in which it is favorable to put local phase slips. However, these are really bound topological defects, which do not destroy the elasticity of the system at long distances. To destabilize the elastic state, one needs to introduce extensive, i.e. unbound L defects.

Instead of a balance between energy and entropy, therefore, we must consider a balance between strain energy and disorder energy. Let us consider these two contributions. The dimensionality of vortex or dislocation defects depends upon d. For d=2, 3, and 4, they are point, line, and surface defects, respectively. In general, the defect dimensionality is tex2html_wrap_inline3796 . In each case, there is at least a core energy cost, because the phases must have large gradients in this core region (one may think of this core region in the continuum as one in which tex2html_wrap_inline3798 is reduced to zero). This core energy is always positive and scales as


What about the energy change from the rest of the region? Consider placing the defect in the center of the size L region. In d=2, place a vortex in the center of a circle; in d=3, anchor two ends of a vortex line in the centers of two ends of a cylinder; etc. Now we can draw a hyper-surface from the core to the boundary of the region. In d=2, this is a radial line, in d=3 a fin-like surface. Now we should calculate the ground state energy of this system given that we allow tex2html_wrap_inline3438 to change discontinuously by a multiple of tex2html_wrap_inline2792 across this hypersurface. In fact, we should also allow the position of this surface to be optimized.

For d>4, we can answer this question very solidly. Recall that in this case in the elastic limit, the strain energies dominated over the disorder, and we had only bounded displacements of u. The random contribution to the ground state energy therefore simply scales as tex2html_wrap_inline3818 , because the medium cannot take advantage of spatially variations in the potential. Now let us suppose we place a vortex in the system. We can go to radial coordinates, in which tex2html_wrap_inline3820 are parallel to the defect, and r and tex2html_wrap_inline2978 are perpendicular to it. Then let tex2html_wrap_inline3826 . Making this change of variables gives


where c is a constant. Because elasticity dominates for d>4, one can safely perturb in tex2html_wrap_inline3644 . To a very good approximation, then, tex2html_wrap_inline3834 , and one has


The energy difference between the vortex ground state and the elastic one is thus


where c' and c'' are other constants. The first term is just the elastic strain energy, the second is the core energy, and the third is the disorder energy. For large L, the sum is always positive, since d>4. So for d>4, the pinned state is certainly stable, at least for weak disorder, to the introduction of topological defects.

As is apparent from Eq. 201, this energy balance changes once d<4. This of course reflects the non-trivial nature of the fixed point in low dimensions. What can we say about this most important limit?

Very little can really be said persuasively. A rough scaling argument suggests that the problem is a marginal one, and therefore leads to no definite conclusion! To see how this works, consider our size L system. We would like to know how the energy changes if we allow the system to include the defect. As we have seen, this is equivalent to allowing ``twisted'' boundary conditions across a surface connecting the defect core and the system boundary. As before, there is a core contribution to the energies of twisted systems. If we include this explicitly, we should be able to ``remove'' the core and replace the system by an annulus with twisted boundary conditions. If one unrolls this annulus into a strip, the energy we are asking for is closely related to the usual stiffness. This should be controlled by the energy exponent tex2html_wrap_inline3850 , so that


This scales in the same way as the core energy, Eq. 198. This means that vortices are marginal. Are they marginally relevant or marginally irrelevant? Naively, if the disorder is weak, then we would expect the core energy to dominate, and vortices to be excluded.

However, this naive argument is suspect in the marginal case. Often times, there are extremely subtle logarithmic effects which favor one phase over another. It is easy to see that this may be the case here. Indeed, by making the same change of variables as for d>4, one may show that


with c>0 as before. This is another consequence of statistical rotational invariance. It means that Eq. 202 cannot be quite correct. Several possibilities exist:

1. tex2html_wrap_inline3856 has a mean value of tex2html_wrap_inline3858 , with much smaller sample-to-sample variations of order tex2html_wrap_inline3180 .

2. tex2html_wrap_inline3856 has a mean value of tex2html_wrap_inline3858 , with comparable or larger (in prefactor) sample-to-sample variations which scale in the same way (i.e. with the same logarithmic factor).

3. tex2html_wrap_inline3856 has a mean value of tex2html_wrap_inline3858 , with symmetric sample-to-sample variations which are larger in a scaling sense (perhaps logarithmically larger?).

4. tex2html_wrap_inline3856 has a mean value of tex2html_wrap_inline3858 . In a typical sample, however, tex2html_wrap_inline3856 is actually of order tex2html_wrap_inline3876 . The logarithm arises due to extremely rare samples with anomalous large (positive) coefficients, whose contribution grows somehow slowly with system size.

5. Our argument is completely incorrect, and the typical energy differences scale in a way unrelated to tex2html_wrap_inline3850 .

In case 1, the elastic state would be stable to disorder, while cases 2 and 3 would be unstable. Cases 4 would probably indicate instability, while case 5 indicates only our ignorance!

There are several other attacks at this issue in the literature. Kierfeld, Natterman, and Hwa use various arguments to argue that case 5 obtains in three dimensions, and that vortices are strongly irrelevant. I find their arguments somewhat unconvincing. Gingras and Huse have attempted to study the problem numerically, using a lattice random-field XY model. In two dimensions, they show convincingly that vortices unbind for arbitrarily weak disorder. This is not surprising, since vortices are marginal in the pure system in d=2, and disorder should only make them more relevant. They also find some evidence for the existence of the topologically ordered phase in d=3, but cannot rule out a weak instability (i.e. that the minimum size of unbound vortices diverges rapidly with decreasing disorder, and thus quickly exceeds their system size). Clearly, this is an important open problem, which would profit from some new insights.

next up previous contents
Next: Plastic phases Up: Beyond the elastic approximation Previous: Beyond the elastic approximation

Leon Balents
Thu May 30 08:21:44 PDT 1996